Chemistry

Get Adobe Reader

2006, No. 9



V.A.Ermokhin, P.P.Purygin, Y.P. Zarubin

SYNTHESIS OF 1-ADAMANTOYL DERIVATIVES OF ESTERS AND AMIDES OF 4-AMINOBENZOIC ACID

A series of 1-adamantanecarboxamides are synthesized from anestezin, procain, procainamid, metoclopramid. Prepared derivatives will be tested on a biological activity.


A.A. Kudryashova, L.A. Onuchak, S.Yu.Kudryashov, O.B.Akopova

SORPTION PROPERTIES OF DISCOTIC LIQUID CRYSTAL 2,3,6,7,10,11-HEXA(4-n-UNDECYLOXYBENZOYLOXY) TRIPHENYLENE IN GAS-MESOPHASE CHROMATOGRAPHY CONDITIONS

In the paper sorption of saturated and aromatic hydrocarbons by discotic liquid crystal 2,3,6,7,10,11-hexa(4-n-undecyloxybenzoyloxy) triphenylene in gas-mesophase chromatography conditions is considered. It is found, that sorption of non-mesogenes leads to formation of an anisotropic solution with strongly expressed negative deviations from ideal behaviour (from Raul’s law). Non-ideality is amplify with reduction of molecular volume of dissolved nonmesogene, and also at transition from saturated to aromatic hydrocarbons.


I.S. Lipatov, Yu.V.Tezikov, E.V. Zubkovskaya, O.V.Maksimova, M.A. Esartiya, I.A.Potapova, V.V.Vishnyakov, P.P.Purygin

BIOMODYLATION MECHANISMS VISIBLE AND INFRA-RED POLARIZED LIGHT

During organizational experiment the data on anti-inflammatory, immunomodylative, woundhealing and action of visible and infra-red polarized light normalizing a metabolism are received. The basic trigger and molecular mechanisms of action are allocated. Recommendations on its further studying and application are given.


Yu.P. Frolov

ASPECTS OF POLYPEPTIDES AND NUCLEIC ACIDS COEVOLUTION

Based on the phenomenon of polypeptides and nucleic acids equispiralic secondary structure a possible way of their coevolution is considered for protobionts.